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In the anime, we're introduced to him as he defeats Rex Raptor in a duel and takes his rarest card (Serpent Night Dragon) because he's "psychic"

Dark Illusion, Fiendish Chain, Skill Prisoner good negate cards, Dark Illusion works for Spells/Traps and monster effects, and fiendish chain also stops the monster from attacking which makes it easy to destroy it later with the monster effects of the barrel dragons that you might get anyway, Skill Prisoner is great to protect the effect monsters or the field spell and it works twice

Note that many of these overlap with a sacrifice theme

Although Pokmon TCG gives plenty of different Pokmon their time to shine, the TCG always makes sure to go all out for collectible Kanto Pokmon, and Mew is no exception